You are correct. The web is always L3, the top flange (if existent) is always L2 and the bottom flange (if existent) is always L4. The only exception to this is with the grid stiffened family. In that family, the 0 degree web is L3, the 90 degree web is L2 and the angled web is L4 (note there are no flanges in the grid stiffened family. Also note that hyperlaminates or hyperlayups can only be used for stiffeners, therefore you cannot use them for facesheets, etc.